Fixed Bed Column Study Using Durian Peel Activated Carbon for Methylene Blue Removal
Abstract
The textile industry is a major contributor to global environmental pollution, particularly through the release of hazardous chemicals such as synthetic dyes like Methylene Blue (MB). This study explores the use of activated carbon derived from durian peel (DZAC) for the removal of MB from wastewater. DZAC was prepared using carbon dioxide and nitrogen gasification combined with microwave heating. The material was characterized and its adsorption efficiency evaluated in a fixed-bed column setup. The results demonstrated that DZAC possesses a high adsorption capacity, with a specific surface area of 1500 m²/g and a total pore volume of 0.75 cm³/g. Optimal adsorption conditions were identified at a lower flow rate (30 mL/min), greater bed height (20 cm), and higher initial contaminant concentration (50 mg/L). Under these conditions, a breakthrough time of 180 minutes was observed. Breakthrough models, particularly the Thomas model, accurately predicted the adsorption behaviour, with a high correlation coefficient (R² > 0.95), confirming the practical applicability of DZAC in wastewater treatment. This study highlights the potential of utilizing agricultural waste for environmental remediation, aligning with sustainable development goals, and providing an effective solution for wastewater treatment.
References
Munonde, T., Nqombolo, A., Hobongwana, S., Mpupa, A., & Nomngongo, P. (2023). Removal of methylene blue using MnO₂@rGO nanocomposite from textile wastewater: Isotherms, kinetics and thermodynamics studies. Heliyon, 9, e15502. https://doi.org/10.1016/j.heliyon.2023.e15502.
Oladoye, P., Ajiboye, T., Omotola, E., & Oyewola, O. (2022). Methylene blue dye: Toxicity and potential technologies for elimination from (waste)water. Results in Engineering, 16, 100678. https://doi.org/10.1016/j.rineng.2022.100678.
Sim, N. L., Ong, C. L., & Ooi, K. C. (2024). Functional properties and continuous adsorption process of durian peel-based activated carbon for aqueous methylene blue removal. Materials Chemistry and Physics, 322, 129484. https://doi.org/10.1016/j.matchemphys.2024.129484.
Urbina-Suarez, N., Angel-Ospina, A. C., López-Barrera, L., Barajas-Solano, A., & Machuca-Martínez, F. (2024). S-curve and landscape maps for the analysis of trends on industrial textile wastewater treatment. Environmental Advances, 15, 100491. https://doi.org/10.1016/j.envadv.2024.100491.